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Handbook of Reagents for Organic Synthesis
Reagents for Silicon-Mediated Organic Synthesis, Handbook of Reagents for Organic Synthesis
ISBN/EAN: 9780470710234
Umbreit-Nr.: 1502793
Sprache:
Englisch
Umfang: 854 S.
Format in cm:
Einband:
gebundenes Buch
Erschienen am 14.10.2011
Auflage: 1/2011
- Zusatztext
- InhaltsangabePreface xiii Introduction xv Reagent Finder Table xxiii Short Note on InChIs and InChIKeys xxxi 3Acetoxy2trimethylsilylmethyl1propene 1 Allyl(2chloroethyl)dimethylsilane 9 Allyl Trichlorosilane 10 Allyltrimethylsilane 14 Allyltrimethylsilylzinc Chloride 24 Ammonium Hexafluorosilicate 25 Azidotrimethylsilane 26 Benzene, [[Difluoro(trimethylsilyl)methyl]seleno] 33 Benzene, [[Difluoro(trimethylsilyl)methyl]thio]- 36 Benzene, [[(1E)-2-(Trimethylsilyl)ethenyl]seleno] 39 Benzene, [[(1E)-2-trimethylsilyl)ethenyl]sulfonyl]- 42 2,1Benzoxasilole, 1,3Dihydro1,1dimethyl 43 NBenzylN(methoxymethyl)Ntrimethylsilylmethylamine 44 1,2Bis(tbutyldimethylsilyl)hydrazine 46 1,2Bis(chlorodimethylsilyl)ethane 48 1,4Bis(dimethylamino)1,1,4,4tetramethyldisilethylene 50 Bis(1methoxy2methyl1propenyloxy)dimethylsilane 51 Bis(methylthio)(trimethylsilyl)methane 52 [Bis(2pyridyldimethylsilyl)methyl]lithium 54 1,3Bis(triisopropylsilyl)propyne 56 N,OBis(trimethylsilyl)acetamide 58 (1E,3E)1,4Bis(trimethylsilyl)1,3butadiene 73 Bis(ßtrimethylsilylethanesulfonyl)imide 74 N,OBis(trimethylsilyl)hydroxylamine 75 Bis[(trimethylsilyl)methyl]zinc 76 Bis(trimethylsilyl) Peroxide 79 Bis(trimethylsilyl) Selenide 82 Bis(trimethylsilyl) Sulfide 83 Bromomagnesium Hexamethyldisilazide 85 (Bromomethyl)chlorodimethylsilane 85 Bromotrimethylsilane 92 (E)1Bromo4trimethylsilyl1buten3yne 100 (Z)2Bromo1(trimethylsilyloxy)ethylene 105 2Bromo3trimethylsilyl1propene 106 (1Bromovinyl)trimethylsilane 109 tButyldimethylchlorosilane 110 tButyldimethylsilyl Cyanide 120 (tButyldimethylsilyl)diphenylphosphine 121 2tButyldimethylsilyl1,3dithiane 122 O(tButyldimethylsilyl)hydroxylamine 124 N(tButyldimethylsilyl)Nmethyltrifluoroacetamide 125 tButyldimethylsilyl Trifluoromethanesulfonate 127 tButyldiphenylchlorosilane 135 1tButylthio1tbutyldimethylsilyloxyethylene 138 1tButylthio1tbutyldimethylsilyloxypropene 141 tButyl Trimethylsilylacetate 147 3Butyn2ol, 4(Trimethylsilyl) 148 Chlorodiisopropylsilane 151 Chlorodimethylsilane 156 Chlorodimethylvinylsilane 157 Chlorodiphenylsilane 162 (Chloromethyl)dimethylphenylsilane 162 (E)(3Chloro1methyl1propenyl)trimethylsilane 166 1Chloro1methylsiletane 166 Chlorotrimethylsilane 170 Chlorotriphenylsilane 182 Cyanotrimethylsilane 184 Diazo(trimethylsilyl)methyllithium 191 (Dibromomethyl)trimethylsilane 197 Ditbutylchlorosilane 198 Ditbutyldichlorosilane 201 trans1,1Ditbutyl2,3dimethylsilirane 207 Ditbutylsilyl Bis(trifluoromethanesulfonate) 209 Dichlorodiisopropylsilane 222 Dichlorodimethylsilane 228 1,3Dichloro1,1,3,3tetraisopropyldisiloxane 230 1,1Dichloro2,2,2trimethyl1phenyldisilane 233 Dicyanodimethylsilane 234 1,2Diethoxy1,2bis(trimethylsilyloxy)ethylene 235 N,NDiethylaminodimethylsilane 237 Diethyl[dimethyl(phenyl)silyl]aluminum 237 Diiododimethylsilane 238 Diisopropyl Chlorosilane, Polymer-supported 240 Diisopropylsilyl Bis(trifluoromethanesulfonate) 241 Dilithium Cyanobis(dimethylphenylsilyl)-cuprate 248 (a,aDimethylallyl)trimethylsilane 252 (2Dimethylaminomethylphenyl)phenylsilane 253 Dimethyl(phenyl)silane 254 Dimethylphenylsilyllithium 255 1,1Dimethylsilacyclobutane 261 Dimethylthexylsilyl Chloride 263 Dimethylthexylsilyl Trifluoromethanesulfonate 265 1,3,2Dioxaborolane, 2(Dimethylphenylsilyl)4,4,5,5 tetramethyl, 1,3,2Dioxaborolane, 4,4,5,5Tetramethyl 2(methyldiphenylsilyl), 1,3,2Dioxaborolane, 4,4,5,5 Tetramethyl2(triphenylsilyl) 270 Diphenyldifluorosilane 276 Disilane, 1,1,1,2,2,2-hexamethyl- 278 1Ethoxy1(trimethylsilyloxy)cyclopropane 285 Ethoxy(trimethylsilyl)acetylene 289 Ethyl Lithio(trimethylsilyl)acetate 293 Ethyl (Methyldiphenylsil
- Kurztext
- Reagents for Silicon-Mediated Organic Synthesis Silicon reagents are usually low-cost, versatile and allow a wide range of reactions. For the selection the Editor focused on three key synthetic approaches with the greatest impact: * Use of silicon as a "temporary tether" by unifying a reactive pair of functional groups and taking advantage of their template-biased intramolecular cyclization * The specific use if the silane functionality as a hetro t-butyl group, often colloquially referred to as the use of silicon as a "fat proton". * The use of the Brook rearrangement as an "anion relay stratagem". A new feature in this Handbook is the reagent finder, and alphabetically organized lookup table arranged by organic functionality and specific structure of the silicon atom to which it is bound. All the information compiled in this volume is also available in electronic format on Wiley Online Library. The electronicEncyclopedia of Reagents for Organic Synthesis (e-EROS) includes all the reagents described in this volume plus many more reagents of other types and for other uses. e-EROS allows for text and structure search and has many new and updated entries added every year.
- Autorenportrait
- InhaltsangabePreface xiii Introduction xv Reagent Finder Table xxiii Short Note on InChIs and InChIKeys xxxi 3Acetoxy2trimethylsilylmethyl1propene 1 Allyl(2chloroethyl)dimethylsilane 9 Allyl Trichlorosilane 10 Allyltrimethylsilane 14 Allyltrimethylsilylzinc Chloride 24 Ammonium Hexafluorosilicate 25 Azidotrimethylsilane 26 Benzene, [[Difluoro(trimethylsilyl)methyl]seleno] 33 Benzene, [[Difluoro(trimethylsilyl)methyl]thio]- 36 Benzene, [[(1E)-2-(Trimethylsilyl)ethenyl]seleno] 39 Benzene, [[(1E)-2-trimethylsilyl)ethenyl]sulfonyl]- 42 2,1Benzoxasilole, 1,3Dihydro1,1dimethyl 43 NBenzylN(methoxymethyl)Ntrimethylsilylmethylamine 44 1,2Bis(tbutyldimethylsilyl)hydrazine 46 1,2Bis(chlorodimethylsilyl)ethane 48 1,4Bis(dimethylamino)1,1,4,4tetramethyldisilethylene 50 Bis(1methoxy2methyl1propenyloxy)dimethylsilane 51 Bis(methylthio)(trimethylsilyl)methane 52 [Bis(2pyridyldimethylsilyl)methyl]lithium 54 1,3Bis(triisopropylsilyl)propyne 56 N,OBis(trimethylsilyl)acetamide 58 (1E,3E)1,4Bis(trimethylsilyl)1,3butadiene 73 Bis(ßtrimethylsilylethanesulfonyl)imide 74 N,OBis(trimethylsilyl)hydroxylamine 75 Bis[(trimethylsilyl)methyl]zinc 76 Bis(trimethylsilyl) Peroxide 79 Bis(trimethylsilyl) Selenide 82 Bis(trimethylsilyl) Sulfide 83 Bromomagnesium Hexamethyldisilazide 85 (Bromomethyl)chlorodimethylsilane 85 Bromotrimethylsilane 92 (E)1Bromo4trimethylsilyl1buten3yne 100 (Z)2Bromo1(trimethylsilyloxy)ethylene 105 2Bromo3trimethylsilyl1propene 106 (1Bromovinyl)trimethylsilane 109 tButyldimethylchlorosilane 110 tButyldimethylsilyl Cyanide 120 (tButyldimethylsilyl)diphenylphosphine 121 2tButyldimethylsilyl1,3dithiane 122 O(tButyldimethylsilyl)hydroxylamine 124 N(tButyldimethylsilyl)Nmethyltrifluoroacetamide 125 tButyldimethylsilyl Trifluoromethanesulfonate 127 tButyldiphenylchlorosilane 135 1tButylthio1tbutyldimethylsilyloxyethylene 138 1tButylthio1tbutyldimethylsilyloxypropene 141 tButyl Trimethylsilylacetate 147 3Butyn2ol, 4(Trimethylsilyl) 148 Chlorodiisopropylsilane 151 Chlorodimethylsilane 156 Chlorodimethylvinylsilane 157 Chlorodiphenylsilane 162 (Chloromethyl)dimethylphenylsilane 162 (E)(3Chloro1methyl1propenyl)trimethylsilane 166 1Chloro1methylsiletane 166 Chlorotrimethylsilane 170 Chlorotriphenylsilane 182 Cyanotrimethylsilane 184 Diazo(trimethylsilyl)methyllithium 191 (Dibromomethyl)trimethylsilane 197 Ditbutylchlorosilane 198 Ditbutyldichlorosilane 201 trans1,1Ditbutyl2,3dimethylsilirane 207 Ditbutylsilyl Bis(trifluoromethanesulfonate) 209 Dichlorodiisopropylsilane 222 Dichlorodimethylsilane 228 1,3Dichloro1,1,3,3tetraisopropyldisiloxane 230 1,1Dichloro2,2,2trimethyl1phenyldisilane 233 Dicyanodimethylsilane 234 1,2Diethoxy1,2bis(trimethylsilyloxy)ethylene 235 N,NDiethylaminodimethylsilane 237 Diethyl[dimethyl(phenyl)silyl]aluminum 237 Diiododimethylsilane 238 Diisopropyl Chlorosilane, Polymer-supported 240 Diisopropylsilyl Bis(trifluoromethanesulfonate) 241 Dilithium Cyanobis(dimethylphenylsilyl)-cuprate 248 (a,aDimethylallyl)trimethylsilane 252 (2Dimethylaminomethylphenyl)phenylsilane 253 Dimethyl(phenyl)silane 254 Dimethylphenylsilyllithium 255 1,1Dimethylsilacyclobutane 261 Dimethylthexylsilyl Chloride 263 Dimethylthexylsilyl Trifluoromethanesulfonate 265 1,3,2Dioxaborolane, 2(Dimethylphenylsilyl)4,4,5,5 tetramethyl, 1,3,2Dioxaborolane, 4,4,5,5Tetramethyl 2(methyldiphenylsilyl), 1,3,2Dioxaborolane, 4,4,5,5 Tetramethyl2(triphenylsilyl) 270 Diphenyldifluorosilane 276 Disilane, 1,1,1,2,2,2-hexamethyl- 278 1Ethoxy1(trimethylsilyloxy)cyclopropane 285 Ethoxy(trimethylsilyl)acetylene 289 Ethyl Lithio(trimethylsilyl)acetate 293 Ethyl (Methyldiphenylsil